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- W2097508435 abstract "Abstract End‐functionalized poly(phenylacetylene)s were synthesized by the polymerization of phenylacetylene (PA) using the well‐defined palladium catalysts represented as [(dppf)PdBr(R)] {dppf = 1,1′‐bis(diphenylphosphino)ferrocene}. The Pd catalysts having a series of R groups such as o ‐tolyl, mesityl, C(Ph)CPh 2 , C 6 H 4 ‐ o ‐CH 2 OH, C 6 H 4 ‐ p ‐CN, and C 6 H 4 ‐ p ‐NO 2 in conjunction with silver triflate polymerized PA to give end‐functionalized poly(PA)s bearing the corresponding R groups in high yields. The results of IR and NMR spectroscopies and MALDI‐TOF mass analyses proved the introduction of these R groups at one end of each polymer chain. The poly(PA) bearing a hydroxy end group was applied as a macroinitiator to the synthesis of a block copolymer composed of poly(PA) and poly(β‐propiolactone) moieties. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010" @default.
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- W2097508435 date "2010-10-15" @default.
- W2097508435 modified "2023-10-18" @default.
- W2097508435 title "Synthesis of end-functionalized poly(phenylacetylene)s with well-characterized palladium catalysts" @default.
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- W2097508435 doi "https://doi.org/10.1002/pola.24366" @default.
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