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• W2097549092 endingPage "1471" @default.
• W2097549092 startingPage "1451" @default.
• W2097549092 abstract "Treatment of the tetrahydrothiophene-3,4-diol 5 with 1,1′-thiobis-(1H-benzimidazole) (6) furnished two diastereoisomers of the novel cyclic thionosulfite 4 with different configurations at the pseudo-tetrahedral center of the thiosulfinyl (SS) group. The configuration of the SS group of the major diastereoisomer (isolated in 45% yield) was established to be syn to the thiolane ring, as determined by X-ray crystallographic analysis, while that of the minor diastereoisomer (isolated in 10% yield) was anti. 1H-NMR Spectroscopic analysis clarified that the shielding and deshielding zones of the SS group are similar to those of the well-documented SO group. Characteristic absorptions of the SS group in the IR, Raman, and UV/VIS spectra were assigned on the basis of calculations at the B3LYP/6-31G* level. The reactivity of the SS group toward thermolysis, hydrolysis, and oxidation was examined. The SS group is more resistant toward oxidation than the divalent sulfide S-atom, but is oxidatively converted to the SO group." @default.
• W2097549092 created "2016-06-24" @default.
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• W2097549092 date "2005-06-01" @default.
• W2097549092 modified "2023-10-16" @default.
• W2097549092 title "The Chemistry of the Thiosulfinyl Group: Preparation, Structure, and Spectroscopic and Chemical Properties of Cyclic Thionosulfites" @default.
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• W2097549092 doi "https://doi.org/10.1002/hlca.200590117" @default.
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