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• W2097560844 abstract "Three natural pyrrolizidines, (+)-amphorogynines A and D and (+)-retronecine, have been prepared from a common lactam intermediate. This central compound, in turn, was synthesized in diastereomerically enriched form through a highly selective [2 + 2]-cycloaddition of dichloroketene with a chiral enol ether, followed by Beckmann ring expansion and reduction. Subsequent stereocenters were then cleanly introduced through internal induction." @default.
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• W2097560844 date "2005-09-21" @default.
• W2097560844 modified "2023-10-16" @default.
• W2097560844 title "New Asymmetric Approach to Natural Pyrrolizidines: Synthesis of (+)-Amphorogynine A, (+)-Amphorogynine D, and (+)-Retronecine" @default.
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• W2097560844 doi "https://doi.org/10.1021/jo050983o" @default.
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