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- W2097624766 abstract "An equation is given to correct the effects of the uncompensated resistance Ru between the working electrode and the tip of the Haber—Luggin capillary in an electroanalytical cell. Peak potential difference and peak current data as a function of scan rate and substrate concentration in reversible or quasi-reversible cyclic voltammograms are used. Co(salen) [salen = N,N′-bis(salicylidene)ethylenediamine], which undergoes a quasi-reversible oxidation process in dimethylformamide, was used as a test system. The influence of under- and overcorrection on the calculation of the heterogeneous electron transfer rate constant is shown." @default.
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- W2097624766 date "1992-01-01" @default.
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- W2097624766 title "Numerical method to correct iR drop errors in cyclic voltammetric potential data for (quasi) reversible electrode processes" @default.
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