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• W2097625495 abstract "The crystal structure of Ca2RuD6 has been determined by neutron powder diffraction: space group Fm3m ,K 2PtCl6 structure, as found for other hexahydride salts of group 8 metals with alkaline earth or lanthanide counter ions. No structural phase transition was observed between 340 K and 50 K. The deuterium nuclear quadrupole coupling constant, 54.7 kHz, leads to an ionic character of the Ru–D bond of 76%. The known trends in the behaviour of A2MH6 salts are interpreted in terms of the ionization energies of the cation and the central metal atom. © 2007 Elsevier B.V. All rights reserved." @default.
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• W2097625495 date "2008-07-01" @default.
• W2097625495 modified "2023-09-26" @default.
• W2097625495 title "Neutron powder diffraction and solid-state deuterium NMR studies of Ca2RuD6 and the stability of transition metal hexahydride salts" @default.
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• W2097625495 doi "https://doi.org/10.1016/j.jallcom.2007.05.078" @default.
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