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- W2097629385 abstract "In this work, we demonstrate a simple gas-phase process to synthesize ZnO with exposed reactive {0001} facets without the use of any capping agent. The method is based on controlling the ZnO growth direction, causing it to switch from the typical [0001] to [100], resulting in [100] grown nanowhiskers with exposed reactive {0001} facets. Moreover, these nanowhiskers self-assemble on ZnO hollow spheres to form a three-dimensional hierarchical nanostructure, which stabilizes these nanowhiskers against agglomeration. Such a designed ZnO nanostructure endows the ZnO sensing material with both small crystal sizes and exposed reactive {0001} facets, which leads to greatly enhanced gas sensitivities compared to typical [0001] grown ZnO nanowires. Such reactive-facet-enhanced gas sensitivity is also shown by our calculation of the chemisorption energy of oxygen, based on density functional theory." @default.
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- W2097629385 date "2011-01-01" @default.
- W2097629385 modified "2023-09-23" @default.
- W2097629385 title "Self-assembly of [101̄0] grown ZnO nanowhiskers with exposed reactive (0001) facets on hollow spheres and their enhanced gas sensitivity" @default.
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- W2097629385 doi "https://doi.org/10.1039/c0ce00821d" @default.
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