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• W2097647512 startingPage "18196" @default.
• W2097647512 abstract "A series of molecules capable of releasing of the strong organometallic Lewis acid B(C6F5)3 upon exposure to 254 nm light have been developed. These photo Lewis acid generators (PhLAGs) can now serve as photoinitiators for several important B(C6F5)3-catalyzed reactions. Herein is described the synthesis of the triphenylsulfonium and diphenyliodonium salts of carbamato- and hydridoborates, their establishment as PhLAGs, and studies aimed at defining the mechanism of borane release. Factors affecting these photolytic reactions and the application of this concept to photoinduced hydrosilylation reactions and construction of siloxane scaffolds are also discussed." @default.
• W2097647512 created "2016-06-24" @default.
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• W2097647512 date "2015-01-01" @default.
• W2097647512 modified "2023-10-10" @default.
• W2097647512 title "Photo Lewis acid generators: photorelease of B(C₆F₅)₃ and applications to catalysis" @default.
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• W2097647512 doi "https://doi.org/10.1039/c5dt03008k" @default.
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