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- W2097788197 abstract "Reaction of [{RhCl(C 2 H 4 ) 2 } 2 ] with E(CH 2 CH 2 CHCH 2 ) 2 (E = S, affords the trimeric complexes [RhCl{E(CH 2 CH 2 CHCH 2 ) 2 }] 3 . The structure of the product with E = Se was established by X-ray diffraction. The coordination sphere at each rhodium atom consists of a distorted trigonal bipyramid with two alkene groups from the same selenoether in equatorial positions, one bridging selenium in the third equatorial position and the other in an axial site with a terminal chloride in the other axial site. One- and two-dimensional NMR studies of the compounds suggest that the solid state structure is retained in solution." @default.
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- W2097788197 date "1992-01-01" @default.
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- W2097788197 title "Platinum metal complexes of potentially chelating alkene-thioether and -selenoether ligands: Synthesis of the trimeric complexes [RhCl{E(CH2CH2CHCH2)2}]3 (E S, Se) and the crystal structure of [RhCl{Se(CH2CH2CHCH2)2}]3" @default.
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- W2097788197 doi "https://doi.org/10.1016/s0277-5387(00)83193-9" @default.
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