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• W2097795304 abstract "We investigated the morphological transition of poly(methyl methacrylate-b-perfluorooctylethyl methacrylate) (PMMA-b-PFMA) swollen with CO2. CO2 preferentially swells the fluorinated PFMA domain. While such selective swelling usually enhances the repulsive interaction between block copolymer domains, PMMA-b-PFMA exhibited an order–disorder transition in CO2. Furthermore, a disordered phase emerged at higher pressure and lower temperature. Therefore, CO2 swelling induced a “retrograde” order–disorder transition, where the disordered phase appears at lower temperature, despite the block copolymer neat bulk showing no ODT." @default.
• W2097795304 created "2016-06-24" @default.
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• W2097795304 date "2013-01-01" @default.
• W2097795304 modified "2023-09-30" @default.
• W2097795304 title "Retrograde order–disorder transition of a semi-fluorinated block copolymer induced by supercritical carbon dioxide" @default.
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• W2097795304 doi "https://doi.org/10.1039/c3sm52332b" @default.
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