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• W2097923034 abstract "Abstract The bonding coordination mode of various silanes to ruthenium complexes is discussed on the basis of a detailed analysis of NMR, IR, X‐ray and DFT data. It is now more and more obvious that a continuum exists between the two extreme situations, i.e. formation of a σ‐silane complex or Si–H bond breaking leading to oxidative addition. Within this continuum, secondary interactions involving Si and H play a significant role, in particular for the stabilization of unusual structures or as intermediates in exchange processes. Here, we highlight the criteria allowing the best description of the different bonding modes. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)" @default.
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• W2097923034 date "2006-05-17" @default.
• W2097923034 modified "2023-10-16" @default.
• W2097923034 title "σ‐Silane Ruthenium Complexes: The Crucial Role of Secondary Interactions" @default.
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• W2097923034 doi "https://doi.org/10.1002/ejic.200600151" @default.
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