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- W2097968650 abstract "The synthesis (and full spectroscopic and crystallographic characterization) of new classes of bioorganometallic Ir- and Rh-complexes having β-lactam containing ligands has been achieved in three steps starting from simple precursors. The procedure for preparing these bioorganometallic compounds uses β-lactams having a phenylpyridyl moiety attached to the C4, N1 or C4 and N1 positions simultaneously, and a directed C–H metal-insertion, in the presence of (MCp*Cl2)2 (M = Ir, Rh). Enantiomerically pure 2-azetidinones can be transformed into diastereomeric (at the metal) mixtures of enantiopure metalla-2-azetidinones. Bimetallic 2-azetidinones are also accessible by this approach. The insertion of electron-poor alkynes into the M–C bond of the bioorganometallic complex occurs regioselectively and in excellent yields. Overall, the sequence imine-β-lactam–metalla-β-lactam is a versatile and efficient full methodology to prepare and functionalize unprecedented, novel Ir- and Rh-complexes having β-lactam containing ligands." @default.
- W2097968650 created "2016-06-24" @default.
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- W2097968650 date "2014-01-01" @default.
- W2097968650 modified "2023-10-16" @default.
- W2097968650 title "Synthesis of new bioorganometallic Ir- and Rh-complexes having β-lactam containing ligands" @default.
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- W2097968650 doi "https://doi.org/10.1039/c3ob41354c" @default.
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