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- W2097984676 abstract "The layered sodium cobalt oxide ${mathrm{Na}}_{x}{mathrm{CoO}}_{2}$ is studied by electron diffraction for a wide range of sodium contents, $0.15<x<0.75$. An extensive series of ordered $mathrm{Na}$ ion-$mathrm{Na}$ vacancy superlattices is found beyond the simple hexagonal average structure. The most strongly developed superlattice is found for the composition ${mathrm{Na}}_{0.5}{mathrm{CoO}}_{2}$, which displays ${mathrm{Co}}^{3+}∕{mathrm{Co}}^{4+}$ charge ordering at low temperatures. The structural principle for some of the observed ordering schemes, particularly near $x=0.5$, is, surprisingly, the presence of lines of $mathrm{Na}$ ions and vacancies rather than simply maximized $mathrm{Na}$-$mathrm{Na}$ separations." @default.
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- W2097984676 date "2004-07-02" @default.
- W2097984676 modified "2023-10-16" @default.
- W2097984676 title "Sodium ion ordering in<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>Na</mml:mi></mml:mrow><mml:mi>x</mml:mi></mml:msub><mml:msub><mml:mrow><mml:mi mathvariant=normal>CoO</mml:mi></mml:mrow><mml:mn>2</mml:mn></mml:msub></mml:mrow></mml:math>: Electron diffraction study" @default.
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- W2097984676 doi "https://doi.org/10.1103/physrevb.70.024101" @default.
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