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- W2097996927 abstract "Starting from the cyclopropanol 2, the isomeric cyclopropanol 4 and the β, γ-unsasturated aldehydes 7 and 8 have been produced by a cobalamin-dependant transformation. In traces, the two acetoxycyclopropanes 3 and 6, the saturated aldehydes 5 and 11 and the β,γ-unsaturated aldehyde 9 could be detected (cf. Structural Formulae and Table). Starting from 4 the same products in a rather similar distribution were obtained. The isomerization 2⇄4 as well as the transformations leading to 7,8, and 9 are shown to be mediated by cob(III)alamin (1(III)). The results are explained on the basis of rearranging Co-complexes. The migrations might be driven by the electrophilic nature of the central Co(d6)-atom." @default.
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- W2097996927 date "1984-09-26" @default.
- W2097996927 modified "2023-09-26" @default.
- W2097996927 title "Oxidative Cyclopropanol Opening by Cob(III)alamin" @default.
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- W2097996927 doi "https://doi.org/10.1002/hlca.19840670606" @default.
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