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• W2097998103 abstract "A-Li shuffle: Experimental and computational data are employed to elucidate the mechanistic aspects of the 1,3-lithium shift occurring in the allenyllithium complexes derived from 1-aryl-1-alkynes. A central role is shown to be played by proton donors, resulting in the in situ formation of a transient allene. This highlights the role of water in the reaction mechanism and explains the disconcerting non-reproducibility of “proton-free” reaction procedures." @default.
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• W2097998103 date "2008-12-18" @default.
• W2097998103 modified "2023-10-18" @default.
• W2097998103 title "1,3-Li/H Shift of 1-Aryl-1,2-alkadienyl Reagents: An Experimental and Theoretical Study" @default.
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• W2097998103 doi "https://doi.org/10.1002/chem.200801849" @default.
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