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• W2098003850 abstract "Abstract Hydrosilylation of α,ω‐bis(trimethylsiloxy)methylhydrosiloxane to alkenes in the presence of a catalyst was performed at several temperatures (30–70°C). Comb‐type methylsiloxane oligomers with various alkyl substituted groups in the side chains have been obtained. Not all active ≡SiH groups participate in the reaction. The reaction order, activation energies, and rate constants have been determined. The synthesized oligomers were characterized by 1 H, 13 C, 1 H COSY NMR, and FTIR spectroscopy. Calculations using the quantum‐chemical semiempirical AM1 method for modeling reaction between methyldimethoxysilane [Me(MeO) 2 SiH] and hexene‐1 were performed to evaluate possible reaction paths. For all initial, intermediate, and final products, enthalpies of formation as a function of the distance between ≡CSi≡ bonds are calculated. The hydride addition is energetically more favorable according to the anti‐Markovnikov rule than according to the Markovnikov rule. Comb‐type oligomers were characterized by gel‐permeation chromatography, differential scanning calorimetry, thermogravimetry, and wide‐angle X‐ray diffractometry. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 1176–1183, 2007" @default.
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• W2098003850 date "2007-01-26" @default.
• W2098003850 modified "2023-10-18" @default.
• W2098003850 title "Formation of polymethylsiloxanes with alkyl side groups" @default.
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• W2098003850 doi "https://doi.org/10.1002/app.25734" @default.
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