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- W2098066322 abstract "Abstract Thermal dehydration of Mg(OAc) 2 · 4H 2 O in atmospheric air or dehydration in EtOH produces basic magnesium acetate Mg 5 (μ 3 ‐OH) 2 (OAc) 8 · n L ( I ) with an open three‐dimensional cage structure. X‐ray diffraction study with the use of synchrotron radiation reveals the structure of the hydrated compound Ia with partial occupancy of channels with water molecules ( n L = 1.19H 2 O) as well as the structure of the solvate with EtOH ( n = 2), Ib . All Mg atoms exhibit CN Mg = 6. Heating of Ia in vacuo affords magnesium oxoacetate Mg 3 (μ 4 ‐O)(OAc) 4 ( II ). The crystal structure of II consists of linear μ 4 ‐O‐bridged ribbons further connected to layers by bridging acetate groups, in which Mg atoms exhibit CN Mg = 5 and 6." @default.
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- W2098066322 date "2015-04-01" @default.
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- W2098066322 title "Structural Chemistry of Basic Magnesium Acetates, Mg<sub>5</sub>(μ<sub>3</sub>-OH)<sub>2</sub>(OAc)<sub>8</sub>·<i>n</i>L and Mg<sub>3</sub>(μ<sub>4</sub>-O)(OAc)<sub>4</sub>" @default.
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- W2098066322 doi "https://doi.org/10.1002/zaac.201400547" @default.
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