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• W2098082354 abstract "Based on a large database of tourmaline crystal-structure refinements and associated electron microprobe analyses, the bond length in the triangular (BO 3 ) groups was found to be reasonably constant for all tourmaline species, but the B-O2 and B-O8 are variable as a function of the crystal chemistry. Tourmalines, such as elbaite, tend to have B-O2 distances significantly shorter than the B-O8 distances, whereas others, like povondraite, tend to have B-O2 distances that are longer than their B-O8 bonds. Statistical analysis of the bond-valence contributions for the nine-coordinated X-02, and the six-coordinated Y-O2, Z-08, and Z'-08 bonds-as they relate to the B-O2/B-O8 bond valence-suggest that the Z'-08 bond has the most influence over the geometry of the (BO 3 ) triangle. This study highlights variations in what has otherwise been assumed to be a static site in the crystal structure of tourmaline-group minerals." @default.
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• W2098082354 date "2008-02-01" @default.
• W2098082354 modified "2023-10-16" @default.
• W2098082354 title "Tourmaline chemistry and the IIIB site" @default.
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• W2098082354 doi "https://doi.org/10.2138/am.2008.2599" @default.
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