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• W2098082802 endingPage "3897" @default.
• W2098082802 startingPage "3894" @default.
• W2098082802 abstract "Fluoroalkenes represent a useful class of peptidomimetics with distinct biophysical properties. Current preparations of this functional group commonly provide mixtures of E- or Z-fluoroalkene diastereomers, and/or mixtures of nonfluorinated products. To directly access fluoroalkenes in good stereoselectivity, a Shapiro fluorination reaction was developed. Fluoroalkene products were accessed in one- or two-step sequences from widely available ketones. This strategy should be useful for the preparation of fluorinated analogs of peptide-based therapeutics, many of which would be challenging to prepare by alternate strategies." @default.
• W2098082802 created "2016-06-24" @default.
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• W2098082802 date "2013-07-23" @default.
• W2098082802 modified "2023-10-18" @default.
• W2098082802 title "Preparation of Fluoroalkenes via the Shapiro Reaction: Direct Access to Fluorinated Peptidomimetics" @default.
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• W2098082802 doi "https://doi.org/10.1021/ol401637n" @default.
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