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- W2098179600 abstract "A large number of cis-complexes of the type cis-[CoL(bidentate)]n+ (L = Me2[14] dieneN4, Me4[14] dieneN4, Me5[14] dieneN4 and Me6[14] dieneN4; bidentate = acac, L-α-ala, gly, bpy, phen, ox and en) have been prepared and characterised. Rapid inversion of sec-NH centres of the macrocycle in the trans-[CoX2(L)]n+ complexes (X = Cl, Br) occurs in the presence of diethylamine, to give the N-racemic stereochemistry required in the cis-complexes. Infrared, electronic and 1H nmr spectra are reported." @default.
- W2098179600 created "2016-06-24" @default.
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- W2098179600 date "1983-01-01" @default.
- W2098179600 modified "2023-09-26" @default.
- W2098179600 title "The preparation and characterisation of Cis-Cobalt(III) complexes of the macrocyclic ligands Me2[14] dieneN4, Me4[14] dieneN4, Me5[14] dieneN4 and Me6[14] dieneN4 with chelating ligands (acac, L-α-ala, gly, bpy, phen, ox and en)" @default.
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- W2098179600 doi "https://doi.org/10.1016/s0020-1693(00)82779-6" @default.
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