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• W2098235757 abstract "Herein we describe the first use of disubstituted donors in the palladium-catalyzed trimethylenemethane (TMM) cycloaddition resulting in an enantioselective synthesis of highly substituted pyrrolidines. These cyanoalkyl donors 1 form all-carbon quaternary centers in a catalytic, asymmetric, and intermolecular manner uniquely using diamidophosphite ligands L2 and L3, generating synthetically important chiral building blocks in good yields and selectivities." @default.
• W2098235757 created "2016-06-24" @default.
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• W2098235757 date "2013-02-08" @default.
• W2098235757 modified "2023-09-26" @default.
• W2098235757 title "Regio- and Enantioselective Synthesis of Pyrrolidines Bearing a Quaternary Center by Palladium-Catalyzed Asymmetric [3 + 2] Cycloaddition of Trimethylenemethanes" @default.
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• W2098235757 doi "https://doi.org/10.1021/ja312351s" @default.
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