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• W2098407730 abstract "Cs4C60 is reported as a pure phase for the first time, using low-temperature synthesis. It adopts an orthorhombic distortion of the body-centred tetragonal (bct) A4C60 structure found for K4C60 and Rb4C60 , due to the orientational ordering of the C604– anions with the 6:6 bonds directed along the orthorhombic b-axis. The caesium cations occupy two distinct distorted tetrahedral sites, producing the orientational order to avoid close contact with the five-membered rings of neighbouring C604– anions. The structure-directing influence of large cations on fulleride structures and the implications for Jahn–Teller distortions of the fulleride anions are discussed." @default.
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• W2098407730 date "1998-01-01" @default.
• W2098407730 modified "2023-10-18" @default.
• W2098407730 title "Cs4C60: single phase synthesis and orientational order" @default.
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• W2098407730 doi "https://doi.org/10.1039/a801508b" @default.
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