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- W2098620923 abstract "3-, 5-, 6-, 7- and 8-nitroquinoline as well as 5,7- and 6,8-dinitroquinoline are methylaminated with a liquid methylamine solution of potassium permanganate (LMA/PP) to the corresponding mono- and bis(methylamino)-substituted compounds. 2-Nitroquinoline is aminated with LMA/PP to 2-(methylamino)quinoline. The intermediate methylamino σ-adducts of 3-nitro- and 5,7- and 6,8-dinitroquinoline are detected by 1H-NMR spectroscopy. Quantum chemical calculations for the mononitroquinolines suggest that the experimentally observed regioselectivity of the methylamination is controlled by an interaction of frontal molecular orbitals (FMO) of the reagents." @default.
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- W2098620923 date "1993-08-12" @default.
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- W2098620923 title "Oxidative Methylamination of Nitroquinolines" @default.
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- W2098620923 doi "https://doi.org/10.1002/jlac.1993199301130" @default.
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