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- W2098692983 abstract "On the basis of the electrostatic and donor-acceptor interactions between carboxylated multiwalled carbon nanotubes (MWCNT-COOH) and polyallylamine hydrochloride (PAH), PAH functionalized MWCNT multilayer films ({PAH/MWCNT-COOH}n) were readily formed on a glassy carbon (GC) electrode surface through a layer-by-layer (LBL) self-assembly method. Then, the PAH functionalized MWCNT multilayer films were used as a functional interface to effectively immobilize the ruthenium(iii) ethylenediamine-tetramethylene phosphonate (EDTMP-RuIII) complex through the strong electrostatic and/or hydrogen bonding interactions between -NH2 and -PO3H2 groups. Fourier transform infrared spectroscopy (FT-IR), ultraviolet-visible spectroscopy (UV-vis), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), energy dispersive spectrum (EDS) mapping, and Raman measurements were used to characterize the self-assembly process, structure, composition and morphology of the EDTMP-RuIII/{PAH/MWCNT-COOH}n/GC electrode. In the EDTMP-RuIII/{PAH/MWCNT-COOH}n/GC electrode, the immobilized EDTMP-RuIII complex could directly exchange electrons with the substrate electrode and showed excellent electrocatalytic activity towards iodate reduction. Thus, the fabricated EDTMP-RuIII/{PAH/MWCNT-COOH}n/GC electrode could be used as an electrochemical sensor for iodate detection." @default.
- W2098692983 created "2016-06-24" @default.
- W2098692983 creator A5031699197 @default.
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- W2098692983 date "2014-01-01" @default.
- W2098692983 modified "2023-10-17" @default.
- W2098692983 title "A ruthenium(<scp>iii</scp>) phosphonate complex on polyallylamine functionalized carbon nanotube multilayer films: self-assembly, direct electrochemistry, and electrocatalysis" @default.
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- W2098692983 doi "https://doi.org/10.1039/c3tb21433h" @default.
- W2098692983 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32261303" @default.
- W2098692983 hasPublicationYear "2014" @default.
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