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- W2099014503 abstract "Abstract According to spectroscopic (NMR, IR, UV/Vis) study, the interaction of pentaphosphaferrocene [Cp*Fe(η 5 ‐P 5 )] with trimeric copper pyrazolate [(Cu{3,5‐(CF 3 ) 2 Pz}) 3 ] yields a new compound that is astonishingly stable in solution. Single‐crystal X‐ray analysis reveals unprecedented structural changes in the interacting molecules and the unique type of coordination [Cp*Fe(μ 3 ‐η 5 :η 2 ,η 2 ‐P 5 ){Cu(3,5‐(CF 3 ) 2 Pz)} 3 ]. As a result of the 90° macrocycle folding, the copper atoms are able to behave both as a Lewis acid and as a Lewis base in the interaction with the cyclo‐P 5 ligand." @default.
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- W2099014503 date "2015-07-27" @default.
- W2099014503 modified "2023-10-18" @default.
- W2099014503 title "Remarkable Structural and Electronic Features of the Complex Formed by Trimeric Copper Pyrazolate with Pentaphosphaferrocene" @default.
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- W2099014503 doi "https://doi.org/10.1002/chem.201502085" @default.
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