FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2099123090> ?p ?o ?g. }

• W2099123090 endingPage "511" @default.
• W2099123090 startingPage "503" @default.
• W2099123090 abstract "Retention data for a set of 69 compounds using rapid gradient elution are obtained on a wide range of reversed-phase stationary phases and organic modifiers. The chromatographic stationary phases studied are Inertsil (IN)-ODS, pentafluorophenyl, fluoro-octyl, n-propylcyano, Polymer (PLRP-S 100), and hexylphenyl. The organic solvent modifiers are 2,2,2-trifluoroethanol (TFE); 1,1,1,3,3,3-hexafluoropropan-2-ol (HFIP); isopropanol; methanol (MeOH); acetonitrile (AcN); tetrahydrofuran; 1,4-dioxane; N,N-dimethylformamide; and mixed solvents of dimethylsulfoxide (DMSO) with AcN and DMSO with MeOH (1:1). A total of 25 chromatographic systems are analyzed using a solvation equation. In general, most of the systems give reasonable statistics. The selectivity of the reversed phase-high-performance liquid chromatographic (HPLC) systems with respect to the solute's dipolarity-polarity, hydrogen-bond acidity, and basicity are reflected in correspondingly large coefficients in the solvation equation. We wanted to find the most orthogonal HPLC systems, showing the highest possible selectivity difference in order to derive molecular descriptors using the gradient retention times of a compound. We selected eight chromatographic systems that have a large range of coefficients of interest (s, a, and b) similar to those found in water-solvent partitions used previously to derive molecular descriptors. The systems selected are IN-ODS phases with AcN, MeOH, TFE, and HFIP as mobile phase, PLRP-S 100 phase with AcN, propylcyano phase with AcN and MeOH, and fluorooctyl phase with TFE. Using the retention data obtained for a compound in the selected chromatographic systems, we can estimate the molecular descriptors with the faster and simpler gradient elution method." @default.
• W2099123090 created "2016-06-24" @default.
• W2099123090 creator A5000769187 @default.
• W2099123090 creator A5004099411 @default.
• W2099123090 creator A5012093239 @default.
• W2099123090 creator A5029179936 @default.
• W2099123090 creator A5045665024 @default.
• W2099123090 date "2000-11-01" @default.
• W2099123090 modified "2023-10-13" @default.
• W2099123090 title "Characterizing the Selectivity of Stationary Phases and Organic Modifiers in Reversed-Phase High-Performance Liquid Chromatographic Systems by a General Solvation Equation Using Gradient Elution" @default.
• W2099123090 cites W1495368973 @default.
• W2099123090 cites W1582298305 @default.
• W2099123090 cites W1970092536 @default.
• W2099123090 cites W1970887795 @default.
• W2099123090 cites W1973448046 @default.
• W2099123090 cites W1975798932 @default.
• W2099123090 cites W1981432419 @default.
• W2099123090 cites W1981807415 @default.
• W2099123090 cites W1985418765 @default.
• W2099123090 cites W1987323764 @default.
• W2099123090 cites W1989265296 @default.
• W2099123090 cites W1995603207 @default.
• W2099123090 cites W1997439427 @default.
• W2099123090 cites W2008508905 @default.
• W2099123090 cites W2010321956 @default.
• W2099123090 cites W2017693902 @default.
• W2099123090 cites W2025009623 @default.
• W2099123090 cites W2038278386 @default.
• W2099123090 cites W2049277349 @default.
• W2099123090 cites W2065456012 @default.
• W2099123090 cites W2080124371 @default.
• W2099123090 cites W2080242559 @default.
• W2099123090 cites W2084417503 @default.
• W2099123090 cites W2087047280 @default.
• W2099123090 cites W2087268432 @default.
• W2099123090 cites W2087979964 @default.
• W2099123090 cites W2090162906 @default.
• W2099123090 cites W2093688811 @default.
• W2099123090 cites W2105112971 @default.
• W2099123090 cites W2106192138 @default.
• W2099123090 cites W2163763334 @default.
• W2099123090 doi "https://doi.org/10.1093/chromsci/38.11.503" @default.
• W2099123090 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/11105774" @default.
• W2099123090 hasPublicationYear "2000" @default.
• W2099123090 type Work @default.
• W2099123090 sameAs 2099123090 @default.
• W2099123090 citedByCount "65" @default.
• W2099123090 countsByYear W20991230902012 @default.
• W2099123090 countsByYear W20991230902014 @default.
• W2099123090 countsByYear W20991230902015 @default.
• W2099123090 countsByYear W20991230902016 @default.
• W2099123090 countsByYear W20991230902017 @default.
• W2099123090 countsByYear W20991230902018 @default.
• W2099123090 countsByYear W20991230902020 @default.
• W2099123090 countsByYear W20991230902021 @default.
• W2099123090 countsByYear W20991230902022 @default.
• W2099123090 countsByYear W20991230902023 @default.
• W2099123090 crossrefType "journal-article" @default.
• W2099123090 hasAuthorship W2099123090A5000769187 @default.
• W2099123090 hasAuthorship W2099123090A5004099411 @default.
• W2099123090 hasAuthorship W2099123090A5012093239 @default.
• W2099123090 hasAuthorship W2099123090A5029179936 @default.
• W2099123090 hasAuthorship W2099123090A5045665024 @default.
• W2099123090 hasConcept C112887158 @default.
• W2099123090 hasConcept C118792377 @default.
• W2099123090 hasConcept C148093993 @default.
• W2099123090 hasConcept C161790260 @default.
• W2099123090 hasConcept C166361863 @default.
• W2099123090 hasConcept C178790620 @default.
• W2099123090 hasConcept C179998833 @default.
• W2099123090 hasConcept C185592680 @default.
• W2099123090 hasConcept C2776701986 @default.
• W2099123090 hasConcept C2777463227 @default.
• W2099123090 hasConcept C2779607525 @default.
• W2099123090 hasConcept C2780471494 @default.
• W2099123090 hasConcept C32909587 @default.
• W2099123090 hasConcept C43617362 @default.
• W2099123090 hasConcept C44280652 @default.
• W2099123090 hasConcept C45188465 @default.
• W2099123090 hasConcept C73826308 @default.
• W2099123090 hasConceptScore W2099123090C112887158 @default.
• W2099123090 hasConceptScore W2099123090C118792377 @default.
• W2099123090 hasConceptScore W2099123090C148093993 @default.
• W2099123090 hasConceptScore W2099123090C161790260 @default.
• W2099123090 hasConceptScore W2099123090C166361863 @default.
• W2099123090 hasConceptScore W2099123090C178790620 @default.
• W2099123090 hasConceptScore W2099123090C179998833 @default.
• W2099123090 hasConceptScore W2099123090C185592680 @default.
• W2099123090 hasConceptScore W2099123090C2776701986 @default.
• W2099123090 hasConceptScore W2099123090C2777463227 @default.
• W2099123090 hasConceptScore W2099123090C2779607525 @default.
• W2099123090 hasConceptScore W2099123090C2780471494 @default.
• W2099123090 hasConceptScore W2099123090C32909587 @default.
• W2099123090 hasConceptScore W2099123090C43617362 @default.
• W2099123090 hasConceptScore W2099123090C44280652 @default.
• W2099123090 hasConceptScore W2099123090C45188465 @default.
• W2099123090 hasConceptScore W2099123090C73826308 @default.
• W2099123090 hasIssue "11" @default.

• next