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• W2099168061 abstract "Lock it in: A temporary silicon-based configurational lock (see scheme) has enabled an efficient and fully diastereoselective assembly of the spiroketal subunit of spirofungin A. This complex natural product was synthesized in 20 steps, including a rapid polyketide assembly based on the ring-opening metathesis of a cyclopropenone acetal. It was established that spirofungin A elicited notable antiproliferative activity against several human cancer cell lines and selectively inhibited isoleucyl-tRNA synthetase in vitro." @default.
• W2099168061 created "2016-06-24" @default.
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• W2099168061 date "2007-11-26" @default.
• W2099168061 modified "2023-10-18" @default.
• W2099168061 title "Spirofungin A: Stereoselective Synthesis and Inhibition of Isoleucyl-tRNA Synthetase" @default.
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• W2099168061 doi "https://doi.org/10.1002/anie.200702440" @default.
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