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- W2099176034 abstract "The present Minireview covers the formation and the structural characterization of noble metal carbonyl and hydrido carbonyl complexes, with particular emphasis on ruthenium complexes using formic acid as a carbonyl and hydride source. The catalytic activity of these organometallic compounds for the decarboxylation of formic acid, a potential hydrogen storage material, is also reviewed. In addition, the first preparation of [Ru4(CO)12H4] from RuCl3 and formic acid as well as the catalytic activity of [Ru4(CO)12H4] for the decomposition of formic acid to hydrogen and carbon dioxide are presented." @default.
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- W2099176034 date "2011-03-14" @default.
- W2099176034 modified "2023-09-27" @default.
- W2099176034 title "Hydrogen Generation from Formic Acid Decomposition by Ruthenium Carbonyl Complexes. Tetraruthenium Dodecacarbonyl Tetrahydride as an Active Intermediate" @default.
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- W2099176034 doi "https://doi.org/10.1002/cssc.201000446" @default.
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