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- W2099179938 abstract "Abstract Nitidasin, ein komplexes Sesterterpenoid mit einem seltenen 5‐8‐6‐5‐Kohlenstoffgerüst, wurde aus dem peruanischen Naturheilmittel “Hercampuri” isoliert und ist ein Vertreter einer kleinen Gruppe von polycyclischen Sesterterpenoiden, die eine trans‐Hydrindaneinheit mit einem Isopropylsubstituenten aufweisen. Als erstes Ergebnis unseres allgemeinen Ansatzes zur Synthese solcher Naturstoffe stellen wir die Totalsynthese der Titelverbindung vor. Die Schlüsselsequenz unserer stereoselektiven und konvergenten Route besteht aus der Addition einer komplexen Alkenyllithiumverbindung an ein trans‐Hydrindanon, einer chemoselektiven Epoxidierung und einer Ringschlussmetathese." @default.
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- W2099179938 date "2014-06-24" @default.
- W2099179938 modified "2023-10-18" @default.
- W2099179938 title "Die Totalsynthese von (−)-Nitidasin" @default.
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