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- W2099185714 abstract "Abstract The reactions of readily available vinyl selenones with enantiopure 1,2‐diols, N‐protected‐1,2‐aminoalcohols, and diamines gave substituted enantiopure 1,4‐dioxanes, morpholines, and piperazines, respectively, in good to excellent yields. The same procedure was extended to the synthesis of thiomorpholine, benzodiazepine, and benzoxazepine. The reactions proceeded in one pot, in the presence of base, through a simple and novel application of the Michael‐initiated, ring‐closure (MIRC) reactions. The formed heterocycles constitute a framework that is observed in a large number of pharmaceutical compounds." @default.
- W2099185714 created "2016-06-24" @default.
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- W2099185714 date "2010-11-29" @default.
- W2099185714 modified "2023-10-18" @default.
- W2099185714 title "Synthesis of Enantiopure 1,4-Dioxanes, Morpholines, and Piperazines from the Reaction of Chiral 1,2-Diols, Amino Alcohols, and Diamines with Vinyl Selenones" @default.
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- W2099185714 doi "https://doi.org/10.1002/chem.201002593" @default.
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