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- W2099209084 abstract "The intramolecular Ru(II)-catalyzed radical addition of the 2,2-dichloroacyl pendant group to the 2-oxazolone moiety followed by reductive dechlorination with (TMS)3SiH provides an effective tool for the formation of the chiral 2-amino alcohol synthon in a completely regio- and stereocontrolled manner. The prepared synthon is useful in the preparation of isomers of unusual amino hydroxy acids including the key component of bleomycins." @default.
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- W2099209084 date "1998-09-01" @default.
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- W2099209084 title "The highly enantiocontrolled functionalization of a 2-oxazolone heterocycle by intramolecular radical-based addition. A chiral synthon for 2-amino alcohols which contain three contiguous stereocenters" @default.
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- W2099209084 doi "https://doi.org/10.1016/s0040-4039(98)01515-9" @default.
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