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- W2099229588 endingPage "10418" @default.
- W2099229588 startingPage "10412" @default.
- W2099229588 abstract "Abstract Dimethylamino‐(+)‐camphorenamine reacted with an equimolar amount of Piers’ borane, HB(C 6 F 5 ) 2 , to give the corresponding iminium–hydroborate zwitterionic salt. Being in equilibrium with the parent enamine–HB(C 6 F 5 ) 2 N–B pair, this salt was able to split hydrogen heterolytically, hydrogenating the iminium group in the molecule. Detailed studies revealed that the hydrogen splitting in this reaction proceeded through an intermolecular pathway leading to a bornylamine–HB(C 6 F 5 ) 2 adduct. When the starting enamine is present in excess over HB(C 6 F 5 ) 2 , the produced bornylamine–HB(C 6 F 5 ) 2 adduct breaks up, eliminating free bornylamine and forming the initial camphorenamine– HB(C 6 F 5 ) 2 pair. This results in hydrogenation of the camphorenamine framework in a catalytic fashion." @default.
- W2099229588 created "2016-06-24" @default.
- W2099229588 creator A5010777333 @default.
- W2099229588 creator A5030844947 @default.
- W2099229588 creator A5031669955 @default.
- W2099229588 creator A5036698983 @default.
- W2099229588 creator A5043452704 @default.
- W2099229588 creator A5052591354 @default.
- W2099229588 date "2013-06-20" @default.
- W2099229588 modified "2023-10-18" @default.
- W2099229588 title "Frustrated Lewis Pair Chemistry of Chiral (+)-Camphor-Based Aminoboranes" @default.
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