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- W2099328097 abstract "Abstract Herein, we report on a novel precipitation method to enable LiMnPO4 olivine (LMP) as a cathode material for lithium ion batteries (LIBs) to reach high capacity at high discharge rates. By confining Mn3(PO4)2 precipitation on surface of a precursor seed of Li3PO4, the size of LMP particles is limited to less than 100 nm for a smaller dimension. The cathode material delivers discharge capacities of 145 mAh g−1 at 0.1 C, 112 mAh g−1 at 1 C to 62 mAh g−1 at 5 C (comparable with top three performances [1] , [2] , [3] ). Even if precipitation is one of the versatile strategies to prepare the cathode material, it has not been reported that such a first-tier high performance is obtained from LMP prepared by precipitation methods. When compared with LMP particles synthesized by a conventional co-precipitation method, the performances are recognized to be considerably enhanced. Also, the surface-confined precipitation process described in this work does not involve a ball milling step with a conductive agent such as carbon black [1] , [2] , [4] , [5] , [6] , [7] , [8] , [9] , [10] so that a low cost synthesis is feasible." @default.
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- W2099328097 date "2012-07-01" @default.
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- W2099328097 title "Restricted growth of LiMnPO4 nanoparticles evolved from a precursor seed" @default.
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- W2099328097 doi "https://doi.org/10.1016/j.jpowsour.2012.02.078" @default.
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