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- W2099360326 abstract "Enantioselective synthesis of β-chiral amines has been achieved via copper-catalyzed hydroamination of 1,1-disubstituted alkenes with hydroxylamine esters in the presence of a hydrosilane. This mild process affords a range of structurally diverse β-chiral amines, including β-deuterated amines, in excellent yields with high enantioselectivities. Furthermore, catalyst loading as low as 0.4 mol% could be employed to deliver product in undiminished yield and selectivity, demonstrating the practicality of this method for large-scale synthesis." @default.
- W2099360326 created "2016-06-24" @default.
- W2099360326 creator A5016727969 @default.
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- W2099360326 date "2014-10-29" @default.
- W2099360326 modified "2023-10-12" @default.
- W2099360326 title "Enantioselective CuH-Catalyzed Anti-Markovnikov Hydroamination of 1,1-Disubstituted Alkenes" @default.
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- W2099360326 doi "https://doi.org/10.1021/ja509786v" @default.
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