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• W2099375890 abstract "Abstract The coordination chemistry of the bidentate P,N hybrid ligand 2‐(2′‐pyridyl)‐4,6‐diphenylphosphinine ( 1 ) towards Pd II and Pt II has been investigated. The molecular structures of the complexes [PdCl 2 ( 1 )] and [PtCl 2 ( 1 )] were determined by X‐ray diffraction, representing the first crystallographically characterized λ 3 ‐phosphinine–Pd II and –Pt II complexes. Both complexes reacted with methanol at the P=C double bond at an elevated temperature, leading to the corresponding products [MCl 2 ( 1 H⋅OCH 3 )]. The molecular structure of [PdCl 2 ( 1 H⋅OCH 3 )] was determined crystallographically and revealed that the reaction with methanol proceeds selectively by syn addition and exclusively to one of the P=C double bonds. Strikingly, the reaction of [PdCl 2 ( 1 H⋅OCH 3 )] with the chelating diphosphine DPEphos at room temperature in CH 2 Cl 2 led quantitatively to [PdCl 2 (DPEphos)] and phosphinine 1 by elimination of CH 3 OH and rearomatization of the phosphorus heterocycle." @default.
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• W2099375890 date "2011-01-17" @default.
• W2099375890 modified "2023-10-18" @default.
• W2099375890 title "Pd^IIand Pt^IIComplexes of 2-(2′-Pyridyl)-4,6-diphenylphosphinine: Synthesis, Structure, and Reactivity" @default.
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• W2099375890 doi "https://doi.org/10.1002/chem.201002586" @default.
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