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- W2099395117 abstract "2-Mercaptoethanol reacts selectively with the 5β,6β-epoxy steroids isolated from Withania somnifera substituting the epoxide by a six-membered oxyethylene-2′-thio ring whereas it failed to show such reactivity on 6α,7α-epoxy withasteroids. The structure of the product has been elucidated by spectroscopic methods, especially applying extensive 2D NMR methods. The anticancer activity of withaferin A was lost in the reaction product indicating that its activity is also linked to the free 5β,6β-epoxide functional group." @default.
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- W2099395117 date "2008-03-01" @default.
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- W2099395117 title "Selective reactivity of 2-mercaptoethanol with 5β,6β-epoxide in steroids from Withania somnifera" @default.
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- W2099395117 doi "https://doi.org/10.1016/j.steroids.2007.10.006" @default.
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