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• W2099431004 endingPage "1785" @default.
• W2099431004 startingPage "1776" @default.
• W2099431004 abstract "Five Fe(III)Mn(III) bimetallic compounds [Fe(iqc)(CN)3][Mn(5-Xsalen)]·pMeOH·qMeCN·rH2O [Hiqc = N-(quinolin-8-yl)isoquinoline-1-carboxamide; salen = N,N′-ethylenebis(salicylideneiminato) dianion; X = H(2), F(3, 3a), Cl(4), Br(5)] were prepared by assembling a newly designed mer-Fe tricyanide (Ph4P)[Fe(iqc)(CN)3]·0.5H2O (1) and the respective Mn Schiff bases Mn(5-Xsalen)+. Compounds 2–4 show linear chain structures in which trans-positioned cyanides of the Fe precursor bridge neighbouring Mn atoms, while 5 is a zigzag chain coordination polymer where two cyanide groups of the precursor in the cis mode act as bridges. The structural change from linear to zigzag may arise from the size effect of the halogens. The reversible structural transformation occurs between 3 and 3a upon the solvation-desolvation protocol and the corresponding magnetic behaviours are affected. Furthermore, in 4 and 5, the helical chains are established through hydrogen bonding of solvent molecules. From a magnetostructural point of view, within the linear chain system, the ferromagnetic coupling in 2, contrary to antiferromagnetic interactions in 3–4, is associated with the large torsion angle of Ceq–Fe–Mn–N(O)eq (eq = equatorial) as well as almost the linear Mn–NC angle." @default.
• W2099431004 created "2016-06-24" @default.
• W2099431004 creator A5003736105 @default.
• W2099431004 creator A5005007571 @default.
• W2099431004 creator A5007459616 @default.
• W2099431004 creator A5051254003 @default.
• W2099431004 creator A5052171305 @default.
• W2099431004 creator A5084533800 @default.
• W2099431004 creator A5087652491 @default.
• W2099431004 creator A5088652060 @default.
• W2099431004 date "2012-01-01" @default.
• W2099431004 modified "2023-10-02" @default.
• W2099431004 title "Syntheses, structures, and magnetic characterizations of cyanide-bridged Fe^IIIMn^IIIchains constructed by mer-Fe(<scp>iii</scp>)tricyanide and Mn(<scp>iii</scp>) Schiff bases: Magnetostructural relationship" @default.
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