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- W2099572891 abstract "Li 3 PO 4 impurity was found in hydrothermally grown LiFePO 4 samples made with excess Li. The impurity dissociates in water, leading to an apparent alkaline nature of the LiFePO 4 sample. The impurity can be removed by washing the sample in a neutral buffer solution, after which an increase in specific capacity of the LiFePO 4 sample was observed. Li 3 PO 4 , as an inactive component within the active material, reduces the energy density of LiFePO 4 . Additional experiments were performed to study the reactivity of LiFePO 4 in different environments. It is found that LiFePO 4 decomposes in a strong alkaline solution and the decomposition can be slowed down by carbon coating the material. After prolonged storage in water, the specific capacity of carbon-coated LiFePO 4 is reduced and Fe dissolution is observed. Material degradation is thought to be due to interactions among LiFePO 4 , impurities, and water." @default.
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- W2099572891 date "2008-01-01" @default.
- W2099572891 modified "2023-09-27" @default.
- W2099572891 title "Impurities in LiFePO[sub 4] and Their Influence on Material Characteristics" @default.
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- W2099572891 doi "https://doi.org/10.1149/1.2919105" @default.
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