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- W2099574442 abstract "In situ scanning tunneling microscopy (STM) was employed to investigate the adsorption of C60 on a Ni(II) octaethylporphyrin (NiOEP) adlayer at liquid/Au(111) interface. It was found that C60 molecules tend to form small islands without defined coordination to the underlying NiOEP array. Moreover, increasing the surface coverage of C60 resulted in the formation of multilayers. The mixture of C60 and NiOEP prepared in solution formed separated domains. The results suggested that the C60–C60 interaction is stronger than that of C60–NiOEP and dominated the adsorption of C60 on NiOEP-modified Au(111) surface. This work provides a direct evidence at molecular scale for the coordination of C60 with NiOEP in a two-dimensional assembly, demonstrating that immobilizing C60 at the geometric center of NiOEP on an Au(111) surface in solution is complicated." @default.
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- W2099574442 date "2006-07-01" @default.
- W2099574442 modified "2023-10-18" @default.
- W2099574442 title "STRUCTURES OF Ni(II) OCTAETHYLPORPHYRIN AND C60 AT Au(111) SURFACE INVESTIGATED BY STM" @default.
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- W2099574442 doi "https://doi.org/10.1142/s1793292006000033" @default.
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