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• W2099681523 abstract "Abstract A simple thermal treatment induced transition from Zn 3 (OH) 2 (BDC) 2 (MOF-69c) to Zn 4 O(BDC) 3 (MOF-5) is reported. Phase crystallinity, pore characteristics and hydrogen storage capacities of the resulting crystals were investigated. It is shown that the structural transition from Zn 3 (OH) 2 (BDC) 2 (MOF-69c) to Zn 4 O(BDC) 3 (MOF-5) could be induced by simply employing the optimal thermal treatment conditions of 200 °C for 48 h in open air. The resultant relatively lower specific surface area of MOF-5 crystals compared to MOF-69c was in agreement with the increased pore diameter and decreased hydrogen storage capacity at 1 bar and 77 K." @default.
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• W2099681523 date "2014-01-09" @default.
• W2099681523 modified "2023-10-17" @default.
• W2099681523 title "Thermal treatment induced transition from Zn₃(OH)₂(BDC)₂ (MOF-69c) to Zn₄O(BDC)₃ (MOF-5)" @default.
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• W2099681523 doi "https://doi.org/10.3139/146.110994" @default.
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