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- W2099683447 abstract "Abstract We have developed a technique for the accurate and precise determination of 34S/32S isotope ratios (δ34S) in sulfur-bearing minerals using solution and laser ablation multiple-collector inductively coupled plasma mass spectrometry (MC-ICP-MS). We have examined and determined rigorous corrections for analytical difficulties such as instrumental mass bias, unresolved isobaric interferences, blanks, and laser ablation- and matrix-induced isotopic fractionation. Use of high resolution sector-field mass spectrometry removes major isobaric interferences from O2+. Standard-sample bracketing is used to correct for the instrumental mass bias of unknown samples. Background on sulfur masses arising from memory effects and residual oxygen-tailing are typically minor (" @default.
- W2099683447 created "2016-06-24" @default.
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- W2099683447 date "2008-08-01" @default.
- W2099683447 modified "2023-09-26" @default.
- W2099683447 title "Sulfur isotope measurement of sulfate and sulfide by high-resolution MC-ICP-MS" @default.
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- W2099683447 doi "https://doi.org/10.1016/j.chemgeo.2008.04.017" @default.
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