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- W2099796437 abstract "A remarkable nonanuclear copper(II) complex, 1, with the composition [Cu9(L)4(μ3-OH)4(MeOH)2](ClO4)2, in which L is a pentadentate trianionic Schiff-base ligand with N2O3 donor atoms, has been characterized by analytical, structural and magnetochemical methods. The structure consists of four dinuclear [Cu2L]+ units linked covalently to a central copper atom by four μ3-OH, thus yielding the nonacopper core. Variable-temperature (2–290 K) magnetic susceptibility data of 1, have been analyzed by a “three-J” exchange coupling model (H = −2JŜi·Ŝj), with the simulated coupling constants J′1 = −189.1 cm−1, J′2 = −22.7 cm−1, J′3 = −45.7 cm−1. A rationale for the different strength of antiferromagnetic interactions based on a comparison with those reported in the literature is forwarded." @default.
- W2099796437 created "2016-06-24" @default.
- W2099796437 creator A5021408198 @default.
- W2099796437 creator A5052471303 @default.
- W2099796437 creator A5078676088 @default.
- W2099796437 date "2009-01-01" @default.
- W2099796437 modified "2023-09-25" @default.
- W2099796437 title "A nonanuclear copper(II) cluster incorporating endogenous alkoxo- and exogenous hydroxo bridges containing [Cu3(μ3-OH)] cores" @default.
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- W2099796437 doi "https://doi.org/10.1039/b900711c" @default.
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