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• W2099798958 abstract "Abstract A general approach to the synthesis of nucleoside conjugates containing carborane and metallocarborane complexes, based on Huisgen 1,3‐dipolar cycloaddition (“chemical ligation”), is described. Boron‐cluster‐donors bearing terminal azide or ethynyl groups were prepared in the ring‐opening reaction of dioxane‐boron‐cluster adducts and an azide anion or suitable alkynol‐derived alcoholate nucleophile. Analogous derivatives bearing terminal sulfhydryl groups were also prepared. Nucleosides with various spacers containing terminal azide or ethynyl groups, located within nucleobases or sugar residues, were used as boron‐cluster acceptors. The proposed methodology provides a convenient way to synthesize libraries of boron‐cluster‐modified nucleosides for various applications." @default.
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• W2099798958 date "2008-11-21" @default.
• W2099798958 modified "2023-10-18" @default.
• W2099798958 title "“Chemical Ligation”: A Versatile Method for Nucleoside Modification with Boron Clusters" @default.
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• W2099798958 doi "https://doi.org/10.1002/chem.200801053" @default.
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