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- W2099854511 abstract "Abstract— An imidazole ring photodegradation induced by indole derivatives in oxygen-free aqueous solutions (Λexc= 254 nm) was demonstrated and studied in various systems at low concentration (0.2 mM). The degradation rate was maximal in the indole-imidazole system and decreased when a substituent was present on either or both rings. The degradation rate also depended on pH (maximal at pH ˜ 6) and on imidazole concentration. Results obtained under N2O atmosphere, in the presence and absence of 1 M t-butanol, indicate that the imidazole degradation is promoted by hydrated electrons photogenerated by the indole chromophore. Kinetic analysis of the data confirms this mechanism." @default.
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- W2099854511 date "1978-01-01" @default.
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- W2099854511 title "PHOTODEGRADATION OF THE IMIDAZOLE RING INDUCED BY INDOLE DERIVATIVES IN OXYGEN-FREE AQUEOUS SOLUTIONS" @default.
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- W2099854511 doi "https://doi.org/10.1111/j.1751-1097.1978.tb07558.x" @default.
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