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• W2099951326 abstract "This study addresses Cs+ desorption from a kaolinite (KGa-1b) and an illite (Morris, IL) by quaternary ammonium ions. The Cs+ sorption capacities on the kaolinite and illite were 14 and 24 mmol/kg, respectively. Desorption of Cs+ from Cs+-preloaded kaolinite and illite at different loading levels followed different trends. In general, Cs+ was more readily removed from kaolinite than from illite. The hydrocarbon chain lengths of the alkylammonium ions had strong influences on Cs+ desorption from kaolinite. At the same alkylammonium concentration, the percentage of Cs+ removal from kaolinite increased as the chain length of the alkylammonium ions increased because of a stronger affinity for clay surfaces with a longer chain length. In contrast, initial alkylammonium concentrations had a greater influence on Cs+ removal from illite than surfactant chain length. As the alkylammonium concentrations increased, the percentage of Cs+ desorption increased. For kaolinite, at the same alkylammonium concentration, a higher percentage of Cs+ desorption was achieved when Cs+ loading was low. As the Cs+ loading on kaolinite increased, the percentage of Cs+ desorption decreased. In contrast, a higher percentage of Cs+ desorption was obtained from illite when Cs+ loading was high. The percentage of Cs+ desorption decreased as the Cs+ loading on illite decreased. For kaolinite and illite with higher Cs+ loading, the percentage of Cs+ removal increased logarithmically with the increase in the ratio of hexadecyltrimethylammonium/Cs+. A minimum value of 30 for this ratio is required to achieve 80% Cs+ removal from kaolinite." @default.
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• W2099951326 date "2004-06-01" @default.
• W2099951326 modified "2023-10-18" @default.
• W2099951326 title "Desorption of cesium from kaolinite and illite using alkylammonium salts" @default.
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• W2099951326 doi "https://doi.org/10.1016/j.clay.2003.10.001" @default.
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