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- W2100020223 abstract "Struktur-Wirkungs-Prinzipien von quartären Ammoniumverbindungen als Korrosionsinhibitoren für die Rohöl- und Erdgasförderung wurden anhand von Elektrochemischer Impedanz Spektroskopie (EIS) und Gewichtsverlustmessungen in Systemen C-Stahl/wäßrige NaCl-Lösung (5 Gew.%, CO2-gesättigt) bei T = 298 K und T = 343 K untersucht. Es konnte gezeigt werden, daß in-situ EIS Messungen rasch relativ genaue Resultate über differentielle Inhibitorwirksamkeiten liefern. Aus XPS Untersuchungen an Oberflächen aus Reinsteisen ließen sich Zusammensetzung, Dicke und Inhibitorgehalt der sich auf dem Substrat bildenden inhomogenen 3-D Deckschichten bestimmen. Der Wirkungsmechanismus des verwendeten Inhibitors konnte aus seiner Verteilung innerhalb der 3-D Deckschicht mit dem Konzept der Interphaseninhibition gedeutet werden. Structure efficiency relationships of corrosion inhibitors for oil and gas production Structure efficiency relationships for quarternary ammonium compounds as corrosion inhibitors for oil and gas production were investigated in the system mild steel/aqueous NaCl solution (5 weight%, CO2 saturated) at T = 298 K and T = 343 K by Electrochemical Impedance Spectroscopy (EIS) and weight loss measurements. In-situ EIS measurements rapidly gave relatively accurate results on differential inhibitor efficiencies. Composition, thickness and inhibitor content of the inhomogeneous 3-D protecting layers formed on highly pure iron surfaces were determined by XPS measurements. The inhibition mechanism of the inhibitor used could be determined by its distribution within the 3-D protecting surface layer and is interpreted in terms of the interphase inhibition concept." @default.
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- W2100020223 date "1989-11-01" @default.
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- W2100020223 title "Struktur-Wirkungs-Prinzipien von Korrosionsinhibitoren für die Rohöl- und Erdgasförderung" @default.
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- W2100020223 doi "https://doi.org/10.1002/maco.19890401102" @default.
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