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• W2100024004 abstract "A facile method for the introduction of various substituents at the C-6 position of guanosine and 2′-deoxyguanosine is reported. In a simple, 1-step transformation, tert-butyldimethylsilyl protected guanosine and 2′-deoxyguanosine were converted to the O6-(benzotriazol-1-yl) derivatives via reaction with 1H-benzotriazol-1-yloxy-tris(dimethylamino)phosphonium hexafluorophosphate (BOP) and 1,8-diazabicyclo[5.4.0]undec-7ene (DBU). The easily isolated, stable and storable, O6-(benzotriazol-1-yl) guanosine derivatives upon exposure to a range of nucleophiles, under appropriate conditions, led to the C-6 modified 2-amino purine nucleoside analogues in good yields." @default.
• W2100024004 created "2016-06-24" @default.
• W2100024004 creator A5010134206 @default.
• W2100024004 creator A5021362778 @default.
• W2100024004 date "2009-01-01" @default.
• W2100024004 modified "2023-10-07" @default.
• W2100024004 title "A simple method for C-6 modification of guanine nucleosides" @default.
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• W2100024004 doi "https://doi.org/10.1039/b905298d" @default.
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