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• W2100026244 abstract "Abstract A coordination polymer constructed from the ligand 2, 2′‐bipyridine‐5, 5′‐carboxylate (Bpydc) with hybrid functional groups and the co‐ligand SO 4 2– was synthesized and structurally characterized by single‐crystal X‐ray diffraction. It shows an intriguing structure of parallel infinite Mn–SO 4 double chains resulting from the coordination of SO 4 2– groups to central Mn II atoms. Further linkage of the Bpydc ligands with the Mn–SO 4 double chains gave rise to a three‐dimensional pillar‐layer framework, in which the Mn–SO 4 double chains act as pillars and the Bpydc ligands form the layers. Two types of hydrogen bonds are observed between the SO 4 2– and carboxylate groups. The assembly of the Bpydc ligand and the SO 4 2– co‐ligand with central Mn II atoms results in a binodal (3, 5)‐connected network with a rare 3, 5T1 topology, confirming the feasibility of this strategy in constructing novel architectures. The formation of the dense pillar‐layer framework sustained by Mn‐SO 4 double chains and hydrogen bonds enhances the stability of this coordination polymer and results in a high thermal stability up to 400°C." @default.
• W2100026244 created "2016-06-24" @default.
• W2100026244 creator A5037005452 @default.
• W2100026244 creator A5080579784 @default.
• W2100026244 date "2015-01-26" @default.
• W2100026244 modified "2023-09-27" @default.
• W2100026244 title "Thermally Stable Coordination Polymer with Hybrid Functional Groups and Mn-SO₄Double Chains" @default.
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• W2100026244 doi "https://doi.org/10.1002/zaac.201400454" @default.
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