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- W2100026433 abstract "Efficient syntheses of both enantiomers of the C13–C21 fragment of epothilone molecules have been performed by use of enantiomeric oxiranyl-substituted cyclopropylsulfonates as key intermediates. The latter were obtained by the cyclopropanation of easily available (R)-methyl 2,3-O-isopropylideneglycerate and subsequent manipulation of the functional groups. Asymmetric allylation of 1-formylcyclopropyl pivalate led to an alternative precursor of the target compounds with moderate enantioselectivity." @default.
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- W2100026433 date "2009-04-01" @default.
- W2100026433 modified "2023-10-18" @default.
- W2100026433 title "A cyclopropanol approach to the synthesis of both enantiomers of the C13–C21 fragment of epothilones" @default.
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- W2100026433 doi "https://doi.org/10.1016/j.tet.2009.02.003" @default.
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