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- W2100028521 abstract "Imidodiphosphoryltetrachlorid reagiert mit Alkanolen (C1–C3) zu den Tetraalkylestern und mit Natriumphenolat zum Tetraphenylester der Imidodiphosphorsäure. Die Tetraalkylester (Alkyl = Methyl, Äthyl, n-Propyl) werden auch bei der Umsetzung von Trichlorphosphazenphosphoryldichlorid, Cl3PNPOCl2, mit den entsprechenden Alkoholen gebildet. Die Reinigung der Ester gelingt durch Destillation ihrer Silylderivate und deren anschließender Desilylierung. Die Ester sind über intermolekulare O … H … O-Wasserstoffbrücken assoziiert. Imidodiphosphoric Acid Esters Imidodiphosphoryl tetrachloride reacts with aliphatic alcohols (C1–C3) as well as with sodium phenolate to form tetraalkylesters or tetraphenylesters of the imidodiphosphoric acid, resp. The tetraalkylesters (alkyl = methyl, ethyl, n-propyl) are also formed by reaction of trichlorphosphazene phosphoryldichloride, Cl3PNPOCl2, with the corresponding alcohols. The purification of the esters can be reached by destillation of their silyl derivatives followed by desilylation. The esters are associated by intermolecular O…︁H…︁O hydrogen bonds." @default.
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- W2100028521 date "1977-04-01" @default.
- W2100028521 modified "2023-09-25" @default.
- W2100028521 title "Ester der Imidodiphosphors�ure" @default.
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- W2100028521 doi "https://doi.org/10.1002/zaac.19774300121" @default.
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