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• W2100029293 abstract "The tetrahedral amorphous carbon (ta-C) films with more than 80% sp3 fraction firstly were deposited by filtered cathode vacuum arc (FCVA) technique. Then the energetic nitrogen (N) ion was used to bombard the ta-C films to fabricate nitrogenated tetrahedral amorphous carbon (ta-C:N) films. The composition and structure of the films were analyzed by visible Raman spectrum and X-ray photoelectron spectroscopy (XPS). The result shows that the bombardment of energetic nitrogen ions can induce the formation of CN bonds, the conversion of C–C bonds to CC bonds, and the increase of size of sp2 cluster. The CN bonds are made of CN bonds and C–N bonds. The content of CN bonds increases with the increment of N ion bombardment energy, but the content of C–N bonds is inversely proportional to the increment of nitrogen ion energy. In addition, C≡N bonds are not existed in the films. By the investigation of AFM (atom force microscopy), the RMS (root mean square) of surface roughness of the ta-C film is about 0.21 nm. When the bombarding energy of N ion is 1000 eV, the RMS of surface roughness of the ta-C:N film decreases from 0.21 to 0.18 nm. But along with the increment of the N ion energy ranging from 1400 to 2200 eV again, the RMS of surface roughness of the ta-C:N film increases from 0.19 to 0.33 nm." @default.
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• W2100029293 date "2011-05-01" @default.
• W2100029293 modified "2023-09-27" @default.
• W2100029293 title "Synthesis and structure of nitrogenated tetrahedral amorphous carbon films prepared by nitrogen ion bombardment" @default.
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• W2100029293 doi "https://doi.org/10.1016/j.apsusc.2011.03.039" @default.
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